Abstract
In solutions in DMSO-d6, the products from the condensation of ethanolamine and 1,2- and 1,3-aminopropanols with aldoses are mixtures of the α- and β-pyranose forms, whereas the β-mercaptoethylimines of aldoses have the 1,3-thiazolidine structure. Glucose β-mercaptoethylimine is characterized by ring-chain tautomerism involving the α-pyranose and diastereomeric 1,3-thiazolidine tautomers.
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