Abstract

O,O-alkylenedithiophosphate derivatives of the general formula. ▪ (where M = As, Sb; G = CH 2C(Me 2)CH 2, C(Me 2)C(Me 2), C(Me 2)CH 2CH(Me) and CH(Me)CH(Me)) were synthesized and characterized by elemental analyses and molecular weight determinations. These new complexes are soluble in common organic solvents, and their IR and NMR ( 1H, 31P) spectral data have been used to investigate a plausible geometry. On the basis of mass spectral data the fragmentation pattern of these derivatives has also been discussed.

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