Abstract
The cover picture shows the structures of Tröger's base derivatives in this study. Tröger's base has a compact molecular structure with two chiral nitrogen atoms (upper left). A cyclic diplatinum complex with C-bonded Tröger's base ligand is synthesized and characterized (lower left). This complex undergoes reductive elimination of the cyclic dimer of Tröger's base (bottom right). Due to the conjugated biphenylene groups, the molecule contains the angle between the aromatic planes of Tröger's base, 65–66°, which is much smaller than those previously reported for Tröger's base derivatives (88–114°) (https://doi.org/10.1002/zaac.202100085).
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Zeitschrift für anorganische und allgemeine Chemie
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
