Abstract
AbstractDespite the widespread application of hypervalent iodines, the corresponding λ3‐bromanes are less explored. Herein we report a general, safe, and high‐yielding strategy to access cyclic diaryl λ3‐bromanes. These unique compounds feature reactivity that is appealing and complementary to that of λ3‐iodanes, generating arynes under mild reaction conditions and in the presence of a weak base. Accordingly, formal meta‐selective transition‐metal‐free C–O and C–N couplings may be achieved. Mechanistic studies unambiguously support the aryne generation mechanism.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
