Abstract
Scorpionate chemistry has long featured sandwich complexes with two trispyrazolylborate (Tp) or two bispyrazolylborate (Bp) ligands coordinated to a transition metal. Less common are complexes in which one Tp and one Bp ligand are coordinated to the metal. We report herein five such complexes of NiII, MnII, CoII, or FeII involving Tp and Bp ligands comprising either 3‐phenyl‐4‐cyanopyrazole or 3‐phenylpyrazole, as well as a related CoII complex with two Tp ligands, one of which is coordinated in a κ2 fashion. All complexes feature an agostic interaction with a B–H hydrogen atom.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
