Abstract

Tris-(β-cyanoethyl) amine (TCA) and bis-(β-cyanoethyl) amine (DCA) were prepared by silica- mediated aza-Michael reaction of ammonium hydroxide and acrylonitrile in gram scale. First time TCA was used as a stabilizer of Pd(0) nano/microparticles (TCA-Pd) and efficient reagent in water mediated Suzuki cross coupling reaction. Further DCA and TCA were applied as efficient base, ligand (N,N-ligand) and reaction medium in palla- dium-catalyzed Heck cross coupling reaction. © Global Scientific Publishers 2013.

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.