Abstract
CuY zeolite is a promising catalyst for oxidative carbonylation of methanol to dimethyl carbonate (DMC). In this work, auto-reduction at high temperature and vapor-induced reduction were comparatively investigated to activate the CuY precursors. XPS, XRD as well as CO adsorption demonstrated that methanol as reduction agent can achieve a high proportion of Cu(I) and avoid the formation of Cu(0) as far as possible, which is responsible for the enhanced DMC yield.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.