Abstract
Some of the current directions in research on conducting and superconducting charge-transfer salts based upon tetrathiafulvalene (TTF)π-electron donor molecules are reviewed. Particular emphasis is placed upon new donor molecules, which have been studied with the aim of increasing the dimensionality in the solid state, thereby gaining control over the intermolecular architecture and long-range electron delocalization. Important structural features of the π-donor in this respect are: close intermolecular sulfur—sulfur contacts, attachment of hydrogen-bonding substituents, and extended π-conjugation. The electronic and structural properties of selected TTF derivatives and their salts are discussed. Synthetic schemes are also presented.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
