Abstract

China's annual metallurgical by-product gas production exceeds 1400 billion Nm3, the calorific equivalent of ∼266 million tonnes of coal. The widely-studied blast furnace gas used in hydrogen-enriched carbonic oxide recycling oxygenate furnaces ensures carbon-reduction. Converter gas contains abundant heat resources, equivalent to ∼6.5 million tonnes of coal. Using high-temperature by-product gas online reforming methods to convert thermal energy into chemical energy and combining it with power generation and other industries imparts physical heat recovery exceeding 60%. China's annual coke oven gas (COG) production could support more than 100 million tonnes of direct reduced iron production, thus reducing CO2 emissions by more than 150 million tonnes (nearly 10% of China's steel industry CO2 emissions). We summarise the characteristics, availability, and steel-chemical co-production utilisation of three by-product gases, and discuss the application of COG in direct reduced iron production and development of metallurgical by-product gas utilisation for carbon reduction in China.

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