Abstract
2-Ehtylthiopyridine (L) reacts with CuI (MeCN, r.t.) to afford a 1D chain coordination polymer (CP), [Cu2I2(L)]n in a 75% yield. The latter consists of double-stranded (Cu2I2)n ribbons ligated on both sides by 2-ehtylthiopyridines in a 1,3-N,S bridging manner. In the solid state at 298 K, this CP displays yellow-green photoluminescence (λmax = 550 nm) with a short lifetime (2.4 µs) and a moderate emission quantum yield (16%).
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