CuFeSe2/Cu2Se@C heterostructures as high-rate ultra-stable anodes for sodium ion half/full batteries

Abstract

Transition metal selenides can be potentially implemented as a new generation of sodium storage anode owing to their abundance and high theoretical specific capacity. However, their practical applications are limited by large volume changes and slow kinetics. Therefore, the construction of transition metal selenide heterojunctions with long cycle stability and high capacity as anodes in sodium ion batteries remains challenging. In this study, carbon coated CuFeSe2/Cu2Se heterojunctions (CFS/CS@C) were successfully prepared via a simple aging and annealing strategy. The abundant heterojunction interfaces and carbon layers accelerated charge transfer, promoted the reaction kinetics, enhanced the electrical conductivity, and extended the cycle life. Consequently, the target material yielded ultra-long cycle stability (301.2 mAh/g at 10.0 A/g after 3000 cycles) and excellent rate performance (330.96 mAh/g at 20 A/g). The directly constructed full cell also exhibited remarkable cycling stability (138.6 mAh/g after 200 cycles at 0.5 A/g). Accordingly, this work demonstrated the construction of transition metal selenide composites as high-performance electrochemical energy storage electrodes.