Cubic Phase Prepared in an Anionic/Amphoteric Surfactant/Oleic Acid/Decane/Water System and the Relationship with the Neighboring Phase

Abstract

The formation, properties, and structure of discontinuous cubic phase in the pseudo-ternary system consisting of N'-carboxyethyl N'-hydroxyethyl N-aminoethyl dodecylamide (imidazoriniumbetain), sodium and triethanol amine salt of polyoxyethylene (1.5 mol) myristyl ether sulfate, oleic acid, decane, and water at a constant surfactant/water ratio of 4/6 were studied by means of small-angle X-ray scattering, freeze-fracture transmission electron microscopy, static light scattering, and dynamic rheology to gain an insight in its origin and interrelation with neighboring phases. It was found that the cubic phase occupied a rather wide region in a constructed ternary phase diagram, including from 25 to 45% of decane. Its properties and structural parameters varied with changing the oil content. The decane addition caused the swelling of spherical micellar aggregates. This resulted in an increase of their diameter up to 35 nm, which was ca. nine times larger than that of the initial micelles, and micellar volume fraction (packing fraction) up to 72 vol. %, which was close to the theoretically possible value of 74 vol. % for the close-packed spherical particles. The cubic phase was surrounded by a micellar L1 phase from the water-rich side (separated by a short two-phase region), two-phase region (cubic + oil) from the oil-rich side, and a lamellar phase from the surfactant-rich side. A transition from the L1 phase to the cubic state at the packing fraction of 60 vol. % was caused by an increase in the packing density of micellar aggregates, occurring with the decane addition. When it reached 72 vol. %, the oil started forming a separated phase owing to the inability of micelles to dissolve it. The important observation is that the adjacent phase from the surfactant-rich side was a lamellar one made up of flat bilayers. The preliminary data showed that the lamellar phase coexisted with cylindrical micelles in the intermediate two-phase region separating the cubic and lamellar phases.