Cubic Halide Double Perovskite Nanocrystals with Anisotropic Free Excitons and Self-Trapped Exciton Photoluminescence

Abstract

In this work, we first developed Cs2KBiCl6 cubic double perovskite nanocrystals and a series of morphologically isotropic double perovskite nanocrystals. Different contributions of different elements to self-trapped states were revealed by density functional theory. Meanwhile, these double perovskite nanocrystals exhibit the coexistence of free and self-trapped exciton dual-color photoluminescence. Femtosecond transient absorption spectroscopy can confirm that the double perovskite nanocrystals produce a relatively obvious structural deformation in the excited state. We infer that this can lead to a large deviation of the excitation and emission transition dipoles, thus causing large photoluminescence anisotropy. Most importantly, we observe for the first time that both free exciton emission and self-trapped exciton emission are highly anisotropic, which are comparable to or even better than that of lead halide perovskites. This research paves the way for exploring more possibilities and practical applications.