Abstract
The coexistence of P4+ and P5+ in one complex and the presence of an ethane-like hexaselenodiphosphato ligand, P2 Se64- , are the novel features of the title compounds (see structure, in which R=Et or iPr; OR groups omitted for clarity). The coordination mode of P2 Se64- in these dodecanuclear copper species is unprecedented and has not even been identified in any mixed ligands containing Group 15/16 elements.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.