Abstract

Cu-catalyzed thiolation or selenylation of aryl C-H bonds with diaryl disulfides and diphenyl diselenides was accomplished using a readily removable directing group. This protocol represents a convenient route for the formation of valuable diaryl sulfides or diphenyl selenides. This simple method gives a variety of functionalized diphenyl sulfides or diphenyl selenides in moderate to good yields in a simple and efficient way.

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