Abstract

Abstract Zirconacyclopentadienes, zirconacyclopentenes and zirconacyclopentanes were readily transferred to the corresponding stannacycles in the presence of a catalytic or a stoichiometric amount of CuCl. Without CuCl, the above transfer did not proceed at all or proceeded very slowly. A convenient one-pot procedure for the preparation of spiro stannacyclopentadiene compounds was also developed with CuCl.

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