Abstract
Hitherto unknown N‐imidoyl sulfonimidamides have been synthesized by a Cu‐catalysed mild one‐pot multicomponent reaction of sulfonimidamides, azides, and alkynes in THF at room temperature under air in moderate to good yield. Furthermore, in the presence of molecular oxygen, the N‐imidoyl sulfonimidamides were further oxidized to give N‐oxoimidoyl sulfonimidamides.
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