Abstract
Two new compounds are reported that contain a 1:1 complex of a cis-bis(2,2‘-dipyridylamine)Cu2+ cation and an oxide fluoride [MOF5]2- (M = Nb, Ta) anion in which the polar distortions of the anions are aligned within one-dimensional chains. The bonding and charge on the oxide and fluoride ions and the distortions of the [NbOF5]2- and [TaOF5]2- anions resemble the ferroelectric material lithium niobate.
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