Cu-BTC-derived Cu@C as nano-heater embedded in 3D g-C3N4 for photothermal-coupled photocatalytic CO2 reduction under full-spectrum solar irradiation

Abstract

This study developed a novel Cu@C/NCN-T composite for efficient photothermal catalytic CO2 reduction. The composite, consisting of carbon-coated Cu (Cu@C) derived from Cu-BTC embedded in three-dimensional graphitic carbon nitride (NCN-T), was immobilized on the surface of carbonized wood (C-wood) floating on water, creating a triphase system (CO2, H2O, and catalyst). The optimized composite demonstrated remarkable CO2 photothermal reduction performance, achieving a rate of 31.3 μmol·g-1·h-1. This performance surpassed that of pure NCN-T and Cu@C by 1.6 and 3.8 times, respectively. The combination of Cu and carbon materials endowed Cu@C/NCN-T with excellent light-absorption properties, resulting in a photothermal effect that elevated the surface temperature and facilitated the catalytic reaction. Furthermore, the Schottky junction formed between Cu@C and NCN-T promoted the separation of electron-hole pairs, with Cu@C acting as charge channels. A charge transfer mechanism was proposed to explain these findings. This catalyst engineering approach holds promise for the development of efficient non-noble metal catalysts for rapid CO2 photothermal reduction.