Abstract
CC and l-average CS calculations of degeneracy averaged differential cross sections and Δ m-integral cross sections have been performed for Hez.sbndCO at E = 60 cm −1 and E = 80 cm −1, for HDz.sbndNe at E = 254 cm −1, and for Hez.sbndH 2 at E = 1520 cm −1. The l avz.sbndCS degeneracy averaged differential cross sections are generally in good agreement with the CC cross sections. The previously observed shifts in the diffraction oscillations for odd rotationally inelastic transitions for Hez.sbndCO and HDz.sbndNe do not occur due to proper phase choice and l̄ = l av choice rather than l̄ = 1 or l′. The l avz.sbndCS approximation gives reliable results for most Δ m-integral cross sections except for those σ cs( jm, jm′) cross sections for which the CC cross sections σ( jm; jm′) and σ( jm′; jm) differ by a large amount.
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