Abstract
We report a simple, facile, surfactant-free chemical route to fabricate morphologically different Cu2O nanoparticles such as octahedron, truncated octahedron, hollow octahedron, cube, and sphere by varying the hydrolyzing agents, complexing agent, and reducing agents. Then the componential and morphological evolution of Cu2O nanoparticles have been studied independently, employing different etching agents such as aqueous NaOH, triethylamine (TEA), and oxalic acid solution. Particles of varied shapes and compositions resulted from the etching, and those particles were characterized by different physical methods. The oxidative dissolution of morphologically different Cu2O nanoparticles with different etching agents depends on the exposed crystal planes. During oxidative dissolution in aqueous oxalic acid solution, it is realized that the stability of the (100) crystal plane is higher than that of the (111) crystal plane. Among all the etching reagents used, only oxalic acid exhibits shape transformation of ...
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