Abstract
Equimolar amounts of the proton acceptor 2-aminopyridine 1 and proton donor picolinic acid 2 were solvent-free grinded to give complex 5. X-ray diffraction was used to determine the crystal structure of the new complex 5 that found to be ionic, with proton transfer occurring to the aromatic nitrogen of the 2-aminopyridine moiety. Nonclassical hydrogen bonding exist in the solid state structure of 5, such as, 2-aminopyridine-carboxylic acid supramolecular heterosynthon was carefully investigated and compared to those exist in cocrystals in terms of supramolecular chemistry and crystal engineering. Complex 5 crystallizes in the monoclinic P2(1)/n space group with unit cell parameters of: a = 8.7714(12) A, b = 12.1579(17) A, c = 10.8546(15) A, with α = 90°, β = 110.100(4)°, γ = 90°, and Z = 4. Equimolar amounts of the proton acceptor 2-aminopyridine 1 and proton donor picolinic acid 2 were solvent-free grinded to give complex 5. X-ray diffraction was used to determine the crystal structure of the new complex 5 that found to be ionic, with proton transfer occurring to the aromatic nitrogen of the 2-aminopyridine moiety. Nonclassical hydrogen bonding exist in the solid state structure of 5, such as, 2-aminopyridine-carboxylic acid supramolecular heterosynthon was carefully investigated and compared to those exist in cocrystals in terms of supramolecular chemistry and crystal engineering.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.