Crystallization waves in thin amorphous layers on heat conducting substrates

Abstract

AbstractA crystallization process in thin films is considered, where, driven by the release of the latent heat of fusion, the transformation from an amorphous state to the crystalline state takes place in a progressing wave of invariant shape. The crystallization rate is determined by a rate equation. The influence of the heat loss due to heat conduction into the substrate is taken into account. The resulting system of an ordinary differential equation and an integro‐differential equation is solved numerically using a collocation method. The propagation speed of the wave in dependence on a non‐dimensional heat loss parameter is determined. It turns out that the existence of a self‐sustaining crystallization wave requires the heat loss parameter to be smaller than a certain critical value. (© 2010 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim)