Crystallization, thermal properties, rheological properties, mechanical properties, and morphology of thermoplastic polyurethanes/calcium sulfate whiskers composites

Abstract

The research shows that thermoplastic polyurethane (TPU) which is easy to process has great application potential in practical application. In this study, a calcium sulfate whisker (CSW) with high strength and stability was used as a reinforcing filler to improve the processability of flexible TPU. In this paper, TPU/CSW composites were prepared by the melt blending method, and the effects of modified CSW on the thermal, crystalline, and melt properties, as well as the rheological and mechanical properties of TPU composites were investigated. The results showed that when the mass content of modified CSW was 10%, the maximum values of ΔH c and ΔH m were 222.81°C and 9.24 J/g, respectively, and the thermal properties of the composites were the most stable. When the content of modified CSW is 5%, the maximum impact strength, bending strength, and tensile strength are 50.5 KJ/m2, 38.8 MPa, and 927.7 MPa, respectively, and the mechanical properties of the composites are the best. The excellent stability and high strength of TPU/CSW composites show great promise for various applications in transportation and building materials.