Abstract

Lanthanide orthophosphate ceramics with monazite structure gained broad interest for several industrial applications. The crystallization processes, compressibility and sinterability of monazite-type lanthanum orthophosphate powder hydrothermally synthesized at 200°C as well as mechanical properties of the sintered compacts were investigated. Based on a combination of thermo- and surface area analyses, X-ray diffraction as well as scanning electron microscopy studies it was found that the crystallization process occurs at ∼500°C and the final crystallization of LaPO4 monoclinic phase takes place at 1400°C. The sintered pellets are characterized by a density of 98% of theoretical density, a Vickers hardness of 5.7±0.1GPa and fracture toughness of 1.4±0.1MPam0.5.

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