Abstract

The Tl-Ba-Ca-Cu-O class of type-II high temperature superconductors (HTS) have Tc's as high as 125K. Although they have good critical current values, when a field is applied the weak pinning and consequent flow of magnetic vortices are a major impediment to the usefulness of these materials. Ion irradiation has been shown to enhance the pinning. High quality single crystals, as determined with x-ray precession and HRTEM, with sharp HTS Meissner signals, were irradiated with 1.5 MeV Kr+ and Xe+ ions using the HVEM-Tandem facility at Argonne National Laboratory. Ion beam microstructural modification was studied in-situ using electron diffraction and after irradiation using HRTEM and nano-beam EDS on Tl-1212 and Tl-2212 (numbers designate the stoichiometry Tl-Ba- Ca-Cu-O) single-crystal HTS. After irradiation, microstructure was studied using the JEOL 2010 in the Earth and Planetary Science Department at the University of New Mexico in order to characterize the resulting irradiation-induced nano-size precipitates.

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