Crystallization of amorphous NiTi shape memory alloy fabricated by severe plastic deformation

Abstract

Based on the local canning compression, severe plastic deformation (SPD) is able to lead to the almost complete amorphous nickel-titanium shape memory alloy (NiTi SMA), in which a small amount of retained nanocrystalline phase is embedded in the amorphous matrix. Crystallization of amorphous NiTi alloy annealed at 573, 723 and 873 K was investigated, respectively. The crystallization kinetics of the amorphous NiTi alloy can be mathematically described by the Johnson-Mehl-Avrami-Kolmogorov (JMAK) equation. NiTi SMA with a complete nanocrystalline phase is obtained in the case of annealing at 573 K and 723 K, where martensite phase transformation is suppressed due to the constraint of the grain boundaries. Crystallization of amorphous NiTi alloy at 873 K leads to the coarse-grained NiTi sample, where (001) martensite compound twin is observed at room temperature. It can be found that the martensitic twins preferentially nucleate at the grain boundary and they grow up towards the two different grains. SPD based on the local canning compression and subsequent annealing provides a new approach to obtain the nanocrystalline NiTi SMA.