Crystallization, microstructural evolution, heavy metals migration, and solidification mechanism of blast furnace slag glass-ceramics

Abstract

In recent years, researchers have prepared glass-ceramics using a mixture of multiple solid waste materials, which is an effective and resourceful way to use and store solid waste. However, solid waste usually contains multiple heavy metals, which presents challenges during the mixing and co-solidification processes. In this study, high-performance glass-ceramics with low leaching were prepared from blast furnace slag (BFS). The synergistic curing mechanism of BFS glass-ceramics for heavy metals Cr, Mn, Cu, Zn, Ni, and Co was investigated in detail, as well as the migration pattern and storage state of heavy metals under different heat treatment stages and different Cr contents. The results show that the increases in temperature and Cr2O3 content contribute to the incorporation of heavy metals into the crystal lattice and promote crystal growth. Excessive crystallization of spinel causes aggregation, which further curtails the leaching of heavy metals. The leaching concentration of heavy metals mainly depends on the heavy metal content in the glass network and the degree of network polymerization. Thus, spinel acts as a crystal core for the solidification of heavy metals, while augite and glass phases act as a double barrier to physically encapsulate them, which is effective for the storage of a wide range of heavy metals. Furthermore, the physical and chemical properties of BFS glass-ceramics are consistent with the Chinese industry standard “Glass-ceramics plate for industrial application” (JC/T 2097-2011). This study provides important theoretical support for the synergistic solidification of multiple heavy metals in glass-ceramics, as well as insights into the preparation of glass-ceramics by mixing BFS with other solid wastes.