CRYSTALLIZATION KINETICS OF 2-CHLORO-4,6-DINITRORESORCINOL BY BATCH COOLING CRYSTALLIZATION METHOD

Abstract

Crystallization kinetics of 2-chloro-4,6-dinitroresorcinol in ethanol was studied by the method of intermittent dynamic analysis. The nucleation rate and crystal growth rate of 2-chloro-4,6-dinitroresorcinol under different crystallization temperatures and stirring rates were estimated. The results show that with an increase of crystallization temperature, both the nucleation rate and crystal growth rate increase. It is further found that when the stirring rate increases, the nucleation rate increases and the crystal growth rate decreases. The technological conditions of cooling crystallization of 2-chloro-4,6-dinitroresorcinol were studied. It is found that when the stirring rate is 180 rpm and the solution is cooled slowly to − 8°C, the particle size of the products is even and the highest yield of 2-chloro-4,6-dinitroresorcinol is 40.6%.