Crystallization Extent and Phase Constitution of Slag Films Taken from Continuous Casting Moulds for Stainless Steels

Abstract

Slag film samples were taken from the mould wall after casting of stainless steel slabs of grade 304, 321, 409L and 430, which represent austenitic, ferritic and titanium stabilized stainless steels. The chemical compositions of the samples were analysed and their phases were identified using a combination of scanning electron microscope (SEM), energy dispersive X-ray analysis (EDX) and X-ray diffraction (XRD). Finally the crystallization ratio was determined by SEM. The results show that the chemical compositions of the films during casting differ from the original designed flux composition. Concerning the heat transfer in the mould, the film taken during casting of steel grade 304 showed the highest insulation ability whereas the film taken during casting of steel grade 409L had the lowest insulation ability. The films taken during casting of steel grades 321 and 430 showed average heat insulation abilities. The solidification conditions in the mould during casting of steel grades 304, 321, and 409L matched the solidification requirements of the corresponding steel grades. However, the basicity of the powder for steel grade 430 should be decreased a little in order to improve the lubrication function and counteract sticking tendencies. Perovskite crystals, which usually precipitate at relatively high temperature, were found in the film taken during casting of steel grade 321. This is harmful in view of the safety of the casting process and the surface quality of the slab.