Abstract
The phase-diagram of succinonitrile-pyrene system determined by the thaw-melt method shows the formation of a monotectic (melting point, 143.3°C) and a eutectic (melting point, 55.3°C) at 0.025 and 0.744 mole fractions of succinonitrile respectively. The critical solution temperature is 48.7°C above the monotectic horizontal. Growth behaviour of the parent components, eutectic and the monotectic studied by measuring the rate of movement of the growth front in a capillary suggests the applicability of Hillig-Turnbull equation for the system.
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