Crystallization behavior, thermal property and biodegradation of poly(3-hydroxybutyrate)/poly(ethylene glycol) grafting copolymer

Abstract

The poly(3-hydroxybutyrate)(PHB)/poly(ethylene glycol)(PEG) grafting copolymer was successfully prepared by PHB and acrylate groups ended PEGM using AIBN as initiator. The crystallization behavior, thermal stability and environmental biodegradability of PHB/PEG grafting copolymers were investigated with differential scanning calorimetry (DSC), Thermogravimetric analysis (TGA), wide angle X-ray diffraction (WAXD), scanning electron microscopy (SEM), and Biodegradation test in vitro. In the results, all the grafting copolymers were found to show the X-ray diffraction arising from the PHB crystal lattice, while none of the PEG crystallized peaks could be found even though the graft percent reached 20%. This result indicated that PEG molecules were randomly grafted onto PHB chain. The thermal properties measured by DSC showed that the melting temperature( T m) and glass transition temperature ( T g) were both shifted to lower temperature with the graft percent increasing, and this broadened the narrow processability window of PHB. According to TGA results, the thermal stability of the grafting copolymers is not changed compared to pure PHB. From the biodegradation test, it could be concluded that degradation occurred gradually from the surface to the inside and that the degradation rate could be adjusted by the PEG grafting ratio. In another words, the biodegradation profiles of PHB/PEG grafting copolymer can be controlled. These properties make PHB/PEG grafting copolymer have promising potential applications especially in agriculture fields.