Abstract
The structures of new carbides formed by crystallisation of amorphous Fe1-xCx alloys have been investigated for 0.30<or=x<or=0.32. They change continuously, as a function of x, as shown by diffraction and Mossbauer experiments. These structures are interpreted by applying the chemical twinning model of Andersson and Hyde (1974) between Fe5C2 and Fe2C. The proportions of the various iron sites, which are obtained from the Mossbauer spectra, are in good agreement with the predictions of the above model.
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