Crystalline Phase, Cross-Section, and Temporal Characteristics of Erbium-Ion in Lu3Ga5O12 Crystal

Abstract

An erbium-doped Lu3Ga5O12(LuGG) single crystal was grown by the Czochralski method. The crystalline phase in the grown crystal was analyzed by powder X-ray diffraction. The erbium-ion emission spectra of the crystal were acquired. The erbium-ion emission cross-section (ECS) spectrum was computed from the acquired emission spectrum. The erbium-ion absorption cross-section (ACS) spectrum was computed using the McCumber relationship. The results are discussed in contrast to those computed from the acquired absorption spectrum, and the comparison shows that both methods give consistent results. The temporal characteristics of the emissions were also studied based on 0.98 μm pulse pumping. The study shows that the infrared emissions at 1.0, 1.5, and 2.8 μm show mono-exponentially temporal behavior. Instead, the decays of two visible emissions at 0.56 and 0.67 μm show considerable non-exponential features; each trace can be fitted double-exponentially. The non-exponential behavior is associated with those erbium ions that are present in the form of clusters, which enables non-radiative upconversion depopulation and hence additional contribution to the decay through cross relaxation between the erbium ions in clusters. The study also shows that about half of the erbium ions are present in the cluster state in the studied crystal.