Abstract

The crystalline morphology of poly(dimethylsiloxane) was studied using a scanning electron microscope equipped with a cold stage. Samples of two different molecular weights were used. In both cases, spherulitic morphology is seen, from −70°C, with spherulites of about 100μ in size. Small single crystals of about a micron in size are also seen, and these are attributed to the presence of cyclics.

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