Abstract

Two new crystalline beryllium carboxylate frameworks, formulated as (C2NH8)2[Be4(OH)4(BTC)2] (BCF-1) and (C2NH8)6[Be3(BTC)4] (BCF-2), have been synthesized under solvothermal conditions, where BTC = 1,3,5-benzenetricarboxylate. Topological analyses reveal that BCF-1 has a 3,6-connected rutile topology and BCF-2 exhibits a 3,4-connected cubic-C3N4 topology.

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