Crystal structures of three host–guest complexes of methylsubstituted cucurbit[6]urils and anthracene derivatives

Abstract

Three host–guest complexes of methylsubstituted cucurbit[6]urils host and anthracene derivatives guests were synthesized and structurally characterized by single crystal X-ray diffractions and 1H NMR technique. The hosts are dodecamethylcucurbit[6]uril (DDMeQ[6]), α,α′,δ,δ′-tetramethylcucurbit[6]uril (TMeQ[6]), and hexa-methylsubstituted cucurbituril (HSMeQ[6]) made from 3a-methyl-glycoluril. The guests are 9,10-bis[ N-(aminoethylene)aminomethyl]anthracene (AN1), 9,10-bis[ N-(aminopropylene) aminomethyl]anthracene (AN2) and 9,10-bis[ N-(aminobutylene)aminomethyl]anthracene (AN3). The crystal structures show the compounds 1–3 with stoichiometry of {DDMeQ[6]-AN1} 2+2NO 3 −24H 2O ( 1), {TMeQ[6]-AN2} 2+4NO 3 − 2H 3O +10H 2O ( 2) and {2HSMeQ[6]-AN3} 2+2Cl −25H 2O ( 3) respectively, and the formation of an exclusion or inclusion host–guest complex is dependent on the length of the substituted alkyl chains on the anthracene.