Crystal structures of four complexes of quinquedentate macrocyclic ligands with novel co-ordination geometries containing five-co-ordinate silver(I), six-co-ordinate cadmium(II), six-co-ordinate mercury(II), and seven-co-ordinate cadmium(II)

S Martin Nelson,Stephen G Mcfall,Nigel B Mason,A Hamid Bin Othman,Michael G B Drew

doi:10.1039/c39770000167

Crystal structures of four complexes of quinquedentate macrocyclic ligands with novel co-ordination geometries containing five-co-ordinate silver(I), six-co-ordinate cadmium(II), six-co-ordinate mercury(II), and seven-co-ordinate cadmium(II)

S Martin Nelson, Stephen G Mcfall + Show 3 more

https://doi.org/10.1039/c39770000167

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Journal: Journal of the Chemical Society, Chemical Communications	Publication Date: Jan 1, 1977
Citations: 38

#Macrocyclic Ligands #Pentagonal Bipyramid + Show 8 more

Abstract
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Abstract

Metal complexes of two ‘N5’ macrocyclic ligands are five-co-ordinate (distorted pentagonal plane, M = AgI), six-co-ordinate (distorted pentagonal pyramid, M = CdII or HgII), or seven-co-ordinate (pentagonal bipyramid, M = CdII) depending upon the sizes of the metal ion and macrocycle.

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