Crystal structures and vibrational spectra of L-argininium(2+) bis(tetrafluoroborate) and L-argininium(2+) bis(perchlorate).

Abstract

In the present work crystal structures of (L-ArgH2)(BF4)2 (I) and (L-ArgH2)(ClO4)2 (II) isostructural salts have been determined. They crystallize in triclinic system with space group P1 and Z = 1. Structure features of the (I) and (II) were compared with respective data of previously known (L-ArgH)(BF4) and (L-ArgH)(ClO4) salts with singly charged L-argininium(+) cation. Infrared and Raman spectra of the (I) and (II) are compared with spectra of (L-ArgH)(BF4) and (L-ArgH)(ClO4) salts. The presence of cation and anions and hydrogen bonds between them are reflected in the IR and Raman spectra. The crystals (I) and (II) exhibit second harmonic generation activity.