Crystal Structure, Photophysical Properties and Antibacterial Activity of a Cd(II) Complex with Trans-2,3,4-Trimethoxycinnamic Acid and 4,4'-Bipyridine Ligands.

Abstract

A new coordination polymer {[Cd(C12H13O5)2(4,4'-bpy)(H2O)2]}n (Cd-Tmca-bpy) was constructed with trans-2,3,4-Trimethoxycinnamic acid (HTmca) and 4,4'-Bipyridine (4,4'-bpy) ligands. This complex was structurally characterized on the basis of elemental analysis, infrared (IR) spectroscopy, powder X-ray diffraction and thermogravimetric analyses. X-ray crystallography revealed that the complex was monoclinic, space group C2/c. The Cd(II) ion in the complex was six coordinated, adopting an octahedron geometry. The neighboring Cd(II) ions linked linear ligand 4,4'-bpy molecules to form an infinite 1D chain. The 1D chain was further interlinked by O-H···O and C-H···O hydrogen bonds, resulting in a 3-D supramolecular framework. Meanwhile, the photoluminescence spectrum of the Cd(II) complex at room temperature exhibited an emission maximum at 475 nm. Using the time-dependent density functional theory (TD-DFT) method, the electronic absorption spectra of the Cd(II) complex was predicted. A good agreement was achieved between the predicted spectra and the experimental data. Bioactivity studies showed that the complex exhibited significant inhibition halos against Pseudomonas aeruginosa (P. aeruginosa) and Staphylococcus aureus (S. aureus).