Abstract
Trimeth-yl({tris-[(phenyl-sulfan-yl)meth-yl]sil-yl}meth-oxy)silane (3), C26H32OS3Si, is a new ligand for transition-metal coordination chemistry derived from 3-bromo-2,2-bis-(bromo-meth-yl)propan-1-ol (1), C5H9Br3O, through silylation and following exchange of bromine groups with NaSPh. Silylated thio-ether ligand 3 crystallizes in the centrosymmetric space group C2/c. Bromo-methyl-alcohol 1 crystallizes in the space group P in the triclinic crystal system with four mol-ecules in the asymmetric unit. Analysis of the Hirshfeld surface shows structure-defining inter-actions for bromo-methyl-alcohol 1, resulting in inter-molecular hydrogen bonds between the hydroxyl groups along the a-axis direction.
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