Abstract

The structure of the title compound has been determined by X-ray analysis. It is monoclinic:a = 10.147,b = 10.081,c = 38.627 A, β = 102.27 °,Z = 4,P21/c. The structure was solved by standard methods and refined by least squares to a (conventional)R-factor of 4.7%. The Ru atom is in square-pyramidal configuration: the Ru-S distances (2.286, 2.336A) are significantly different, but the Ru-P distances average to 2.389 A. Comparisons are made with the violet isomer.

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