Abstract
The crystal structure of the [La(DMSO)6(H2O)PW12O40] · C2H5OH complex (I) (where DMSO is dimethyl sulfoxide) is determined by X-ray diffraction analysis. The coordination polyhedron of the La atom is a distorted tricapped trigonal prism in which two cap sites are occupied by oxygen atoms of the heteropolyanions. For these atoms, the La-O distances [2.760(9) and 2.801(9) A] are considerably longer than the other distances [ranging from 2.441(10) to 2.569(10) A] in the environment of the La atom.
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