Abstract

The crystal of the 1:1 complex of hexakis(2,6-di- O-methyl)cyclomaltohexaose with 3-iodopropionic acid is orthorhombic, space group P2 12 12 1, with a = 10.707(1), b = 14.564(3), c = 41.448(4) Å, and Z = 4. The round shape of the host molecule is maintained by the intramolecular ▪ hydrogen bonds. The guest molecule is fully included within the host cavity, with the iodine atom located on the O-6 side. The carboxyl group, located on the O-2,3 side, forms a hydrogen bond with HO-3 of the adjacent host. The host molecules are arranged in a herringbone fashion to form a typical cage-type packing structure.

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