Abstract
The crystal structure of the coordination polymer [Co(bipy)1.5(NO3)2]·1 (bipy=4,4′-bipyridine), reveals that, if crystallized in the presence of CS2, it exists as a novel two-dimensional bilayer motif. This is in contrast to what might have been expected since a one-dimensional molecular-ladder motif is exhibited by 1 when crystallized in the presence of MeCN or CHCl3. A molecule of CS2 is clathrated inside the bilayer via what appear to be C–H···S hydrogen bonds from 4,4′-bipyridine ligands. Adjacent bilayers pack efficiently in a gear-like fashion. The existence of this new structural supramolecular isomer is rationalized on the basis of a template effect from the CS2 guest molecule.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
