Abstract

Abstract The crystal structure of 2,6-diethylnaphthalene thiourea adduct was solved by single crystal X-ray diffraction method. The crystal is monoclinic, space group P2l/c, with a = 12.571(3), b = 9.282(2), c = 14.634(3) Å, β = 92.14(2)°, V = 1706.3(6) Å3 and Z = 2. The final R value was 0.083. The structure was composed of thiourea (host) molecules enclosing channels with hexagonal-prism and 2,6-diethylnaphthalene (guest) molecules in the channels. The cross-section of the channel was deformed hexagon. In the channel, the occupying channel length of the guest molecule was 12.571(3) Å

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