Abstract
The title complex has been prepared and characterized by IR spectroscopy and X-ray crystallography. The crystals are monoclinic, space group P2 1, with a = 9.2010(9), b = 13.044(3), c = 9.888(4) Å, β = 109.35(2)° and Z = 2. The structure has been refined to R F = 0.038 for 288 variables and 3385 observed Mo Kα reflections. The crystal consists of an assembly of [C(NH 2) 3] + cations, [TiO(CO 3) 3] 4− anions, and water molecules which are interlinked by hydrogen bonds to form a three-dimensional network. The coordination geometry about the titanium atom may be described as a distorted pentagonal bipyramid, the axial positions being occupied by the oxo ligand and an oxygen atom of one of the chelating bidentate carbonato ligands.
Published Version
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