Abstract
AbstractThe crystal structure of RbTlI4·2H2O (cubic, ${\rm Fm}{\bar 3}\rm c$, Nr. 226, Z = 24, a = 1993.5(2) pm, 327 unique reflections with Io > 2σ(Io), R1 = 0.0305, wR2 = 0.0702, GooF = 1.1199, T = 298(2) K) is characterized by an ReO3 analogous arrangement of rubidium centered [TlI4] tetrahedra. The cuboctahedral cavities of this structure are filled with crystal water molecules and additional disordered rubidium cations.
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More From: Zeitschrift für anorganische und allgemeine Chemie
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