Abstract
Single crystal of Rb[UO2(SO4)F] (I) was studied by X-ray diffraction [rhombic system, space group Pca21, Z = 12, unit cell parameters: a = 25.393(3), b = 6.735(1), c = 11.496(3) A]. The main structural units of crystals of I are [UO2(SO4)F]- layers belonging to the crystallochemical group AT3M2 (A = UO22+) of uranyl complexes and combined into three-dimensional framework by electrostatic interactions involving interlayer rubidium ions.
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