Abstract
The title polymeric compound, (C7H10N)4[Cd3Cl10], involves a centrosymmetric [Cd3Cl10]4− tetra-anion, which is made up of three face-sharing CdCl6 octahedra, linked by four corner Cl atoms, forming layers propagating in the ab plane. The p-methylanilinium cations, situated between the layers, form N—H...Cl hydrogen bonds to the layers, which stack up the c-axis direction. There are no π–π or C—H...π interactions involving the aromatic rings, which are inclined to each other by 42.3 (1) ° in the asymmetric unit.
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